Accurate Vibrational and Ro Vibrational Contributions to the Properties of Large Molecules by a New Engine Employing Curvilinear Internal Coordinates and Vibrational Perturbation Theory to Second Order Journal of Chemical Theory and COUPLING TYPES 4 1 Definition Couplings are mechanical components used to connect two rotating shafts for transmitting power and torque. They are designed to compensate for misalignment, absorb vibration, and reduce shock Vibration Rotation Interaction Constant an overview ScienceDirect Topics Molecular spectroscopy and excited state dynamics: Diatomics Basicmedical Key